Understanding Self-Discharge in Lead-Acid Batteries

Self-discharge is a natural phenomenon observed in all rechargeable batteries, including lead-acid batteries. It refers to the gradual loss of stored energy when a battery is not in use. For lead-acid batteries, the self-discharge rate typically ranges from 3% to 20% per month, depending on various factors such as temperature, battery design, and manufacturing quality.

Causes of Self-Discharge

  1. Electrochemical Reactions: Lead-acid batteries undergo internal chemical reactions even when idle. The lead plates and sulfuric acid electrolyte react, gradually reducing the charge.
  2. Impurities in Materials: Impurities in the lead or electrolyte can accelerate self-discharge by promoting unwanted side reactions.
  3. Temperature: Higher temperatures significantly increase the rate of self-discharge. For every 10°C rise, the rate approximately doubles.

Impact of Self-Discharge
Excessive self-discharge can lead to a loss of capacity, sulfation of the plates, and reduced battery life. Proper storage and periodic recharging are essential to minimize these effects.

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